Dolomite

Trigonal  Images    

   
   
  Formula CaMg(CO3)2
  Optic class & sign Uniaxial negative
  Relief Low negative to high positive; sections with c close to the thin section plane show a marked change of relief over a 90° rotation; strong chagrin in high-relief position (= polarizer parallel to long diagonal of rhomb).
  Refractive indices no = 1.679
ne = 1.500
n and Δn data for endmember composition; n increases with substitution of Fe or Mn for Mg
  Birefringence   (max.)0.179
   Δn increases with substitution of Fe or Mn for Mg
  Sign of elongation Hardly applicable due to very high Δn
  Interference figure Well-defined isogyre cross, isochromes over multiple colour orders; rarely anomalous biaxial with small 2V
  Colour /   pleochroism Colourless
  Zoning 

  Form  Habit Granular, rarely fibrous
  Surface Anhedral in carbonate aggregates, distributed grains in a matrix may be euhdral; euhedral crystals with curved surfaces in cavities
  Cleavage 3 sets, rhombohedral {1011}, perfect
  Twinning Lamellar on {0221}, 3 sets at 75°, also as deformation twins; simple contact twins on {0001}, {1010}, {1120}
  Extinction Symmetrical to cleavage traces and rhombohedral twin planes in sections subparallel to c. Mottled extinction due to preparation-related, miniscule surface breakouts at cleavage intersections

  Reaction textures  Cooling-related unmixing of dolomite as blebs or stringers in high-temperature magnesian calcite
  Alteration /   decomposition Soluble, but less so than calcite

  Occurence     Ign Carbonatites, alkaline dike rocks, rarely in pegmatites
  Met Pure and impure calcareous-dolomitic metasediments (marble, calcschists, calcsilicate rocks), altered and subsequently metamorphosed ultramafic rocks (e.g., ophicarbonate rocks)
  Sed Dolomitized carbonate sediments, evaporites
  Hyd Veins and cavities; gangue mineral in hydrothermal deposits
  Other 

  Distinctive   properties               High-order white interference colours, rhombohedral cleavage lamellar twins, and relief change between nO and nE (as for all other rhombohedral carbonates).
Routine optical distinction of the two most common carbonates, calcite and dolomite: Select twinned grains with a distinct change of relief when turning the stage; then select position of max. relief (nO parallel to lower polarizer); the orientation of the twins with respect to O and E directions can now be checked (cf. crystal drawings). In dolomite, the twin lamellae are at a low angle to c (i.e., in thin section the angle to ne' is smaller than 40°). Quantitative distinction of different carbonates in a rock by staining or XRD techniques.
  Additional   comments n-Δn chart: Cal - calcite, Dol - dolomite, Kut - kutnahorite, Mgs - magnesite, Rds - rhodochrosite, Sid - siderite, Smt - smithsonite