Viridine

Orthorhombic  Images    

   
   
  Formula (Al,Mn3+,Fe3+)AlSiO5
  Optic class & sign Biaxial positive
  Optical orientation a = X, b = Y, c = Z
  Optical plane (010)
  Relief Moderate-positive to high
  Refractive indices nx = 1.650 -1.705
ny = 1.654 -1.728
nz = 1.662 -1.770
n increases with increasing Mn3+ and Fe3+
  Birefringence   (max.)0.012  - 0.065
   Δn increases with Mn3+ and Fe3+, anomalous interference colours; masking of interference colours by mineral colour
  Optic Angle 2Vx
2Vz = 59 - 85°
  Sign of elongation Length-slow, l (+)
  Interference figure As Mn (and Fe) increase, the simple first-order colour figure of andalusite changes to show increasingly higher-order isochrome rings in optic axis figures. In strongly coloured viridine, the superposition of the mineral colour on the interference colours is evident.
  Colour /   pleochroism Green to yellow pleochroic, absorption Y > Z > X, with X = light yellow to greenish yellow or yellowish green, Y = light to deep emerald green, Z = light to deep golden-yellow; colour distribution may be patchy; absorption increases with increasing Mn
  Zoning 

  Form  Habit Granular, short columnar
  Surface Anhedral to euhedral
  Cleavage 2 sets of {110} prismatic cleavage at nearly 90°
  Twinning 
  Extinction Symmetrical to {110} prism faces and cleavage in sections ⊥ c; straight to prism faces and cleavage in sections parallel to c

  Reaction textures  
  Alteration /   decomposition Sericite, pyrophyllite, with Mn- or Fe oxides

  Occurence     Ign 
  Met Mn-Al-rich metapelitic and semipelitic rocks from oxidising environments
  Sed 
  Hyd 
  Other 

  Distinctive   properties               Green colour and characteristic pleochroism; mineral association
  Additional   comments In accordance with Deer, Howie & Zussman (1997), the name viridine is retained here. Viridine is optically quite distinct from common andalusite, while there is seemingly a continuous solid solution between the two minerals. The CNMNC-approved name for viridine is ferrian manganian andalusite (cf. Gunter & Bloss, 1982, Am. Mineral. 67, 1218-1228). Viridine with up to about 0.5 (Mn3++Fe3+) in octahedral position has been described. The name kanonaite is applied to compositions with Mn3+>Al in the M(1) position, and to the theoretical endmember composition Mn3+AlSiO5. Kanonaite from the type locality has a composition of Mn0.76Fe0.015Al0.23)AlSiO5.