Cordierite

Orthorhombic  Images    

   
   
  Formula (Mg,Fe)2(Si5Al4)O18 ∙ n(H2O,CO2)
  Optic class & sign Biaxial positive or negative
  Optical orientation a = Y, b = Z, c = X
  Optical plane (100)
  Relief Low negative to low positive
  Refractive indices nx = 1.522 -1.560
ny = 1.524 -1.574
nz = 1.527 -1.578
n increases with increasing Fe and Mn and increasing channel occupancy (H2O and CO2); n increases with increasing disorder (indialite has maximum n)
  Birefringence   (max.)0.005  - 0.018
   Δn increases with increasing Fe and Mn and increasing channel occupancy (H2O and CO2)
  Optic Angle 2Vx = 35 - 90°
2Vz = 90 - 74°
  Sign of elongation Length-fast, l (-) for sections elongate in c; direction of elongation is normally not obvious, though.
  Interference figure Most cordierites are optically negative with 2V between 65 and 85°; broad, dark isogyres on a low-birefringence field
  Colour /   pleochroism Colourless; Fe-rich varieties may show pale colour and pleochroism, with Z > Y > X with X = colourless, pale yellow, pale green, Y = pale blue to violet, Z = pale blue
  Zoning 

  Form  Habit Ovoid-shaped crystals in medium-grade schists; irregular shapes in high-grade rocks
  Surface Commonly anhedral; rarely euhedral prismatic
  Cleavage Single set {010}; parting on {001} may be observed
  Twinning Cyclic or sector twins on {110}, arranged as six sectors showing three pairs of sectors ("cross-triplet") with different crystallographic orientation, respectively; twin contacts can be very irregular; lamellar twins on {110}, also on {310}; lamellar twins are particularly common in high-grade rocks. Complex twins of sets of lamellae intersecting at about 60°.
  Extinction Straight to prism faces and cleavage in sections parallel c.

  Reaction textures  Multiple reactions involving cordierite, prograde as well as retrograde, lead to a variety of reaction textures involving, for example, aluminosilicates, garnet, chlorite
  Alteration /   decomposition Common as cordierite is prone to breakdown in the presence of water; "pinite" is the typical material of low-temperature cordierite replacement: a yellow to greenish-yellow aggregate of chlorite and other phyllosilicates, preferentially developed along grain boundaries and fractures; complete pinitisation is not uncommon

  Occurence     Ign Aluminous granites, pegmatites, also gabbros, rarely in andesitic to dacitic volcanic rocks
  Met Regional- and contact-metamorphic pelitic rocks at amphibolite- to granulite-facies conditions, restricted to low-pressure, high-temperature facies series ("Buchan" or "Abukuma" series), including contact hornfelses and migmatites; with ortho-amphibole in Al-poor, Mg-rich rocks of either propylitic alteraton zone or sedimentary origin
  Sed 
  Hyd Quartz veins
  Other 

  Distinctive   properties               Low relief, low birefringence, characteristic twinning if present, and characteristic alteration; pseudo-hexagonal shape if euhedral. Unaltered cordierite may be difficult to distinguish from quartz or feldspar.As opposed to plagioclase twinning, cordierite twin lamellae intersect at different angles and tend to be less regular, tapered in appearance. Cordierite in medium-grade metapelitic rocks tends to form inclusion-rich porphyroblasts, whereas granulite-facies cordierites are commonly inclusion-poor. Distinct yellow pleochroic haloes around zircon and monazite inclusions.
  Additional   comments Indialite: high-temperature polymorph, completely Si-Al-disordered and hence hexagonal