Titanite

Monoclinic  Images    

   
   
  Formula CaTiSiO4(O,OH,F)
  Optic class & sign Biaxial positive
  Optical orientation a near X, b = Y, c Λ Z = 36 - 51°
  Optical plane (010)
  Relief Very high
  Refractive indices nx = 1.843 -1.950
ny = 1.870 -2.034
nz = 1.943 -2.110
n decreases with replacement of Ti by Al and Fe3+
  Birefringence   (max.)0.100  - 0.192
   Δn decreases with replacement of Ti by Al and Fe3+. Max interference colour is a high-order white, in coloured varieties, the mineral colour blends with the interference colour. Sections near-orthogonal to an optic axis show a display of anomalous interference colours when rotating the stage; an extinction position is not defined with polychromatic light.
  Optic Angle 2Vx
2Vz = 17 - 40°
  Sign of elongation Length-fast, l (-) for the long diagonal of (010) sections, but determination is impractical due to very high Δn
  Interference figure Due to high Δn, interference figures show numerous isochromatic rings. Strong optic axis dispersion causes colour fringes on isogyres.
  Colour /   pleochroism Colourless to various shades of pale brown, then weakly pleochroic Z > Y > X, with X = colourless to pale yellow, Y = pale yellow-brown, pale pink, greenish yellow, Z = grey-brown, pink, orange-brown, greenish brown
  Zoning 

  Form  Habit Granular, characteristic rhomb-shaped crystals if euhedral
  Surface Commonly subhedral to euhedral if isolated crystals
  Cleavage {110}, 2 sets, but normally not obvious in thin section
  Twinning Simple twins {100} with twin plane along the long diagonal of the rhomb; also multiple twins on {221}
  Extinction Mostly inclined to crystal faces; symmetrical in rhomb sections

  Reaction textures  Titanite coronas around rutile or ilmenite may be observed
  Alteration /   decomposition Alteration to opaque leucoxene (Ti-oxides, quartz and other minerals). Titanite may form as a product of biotite or Ti-augite alteration.

  Occurence     Ign Most common in silica-undersaturated and intermediate plutonic rocks (syenite, monzonite, granodiorite, diorite); granite pegmatites; phonolite
  Met Ca-rich schists and gneisses, amphibolites, marble, calcsilicate rocks, blueschists
  Sed Detrital in the heavy mineral fraction of sands; also authigenic
  Hyd 
  Other 

  Distinctive   properties               Very high relief and birefringence; characteristic crystal form. Compared to carbonates, the change of relief in max birefringence sections when rotating the stage is far less distinct to the eye.
  Additional   comments Where sufficient radiogenic isotopes are contained in titanite, α-radiation damage creates pleochroic halos in some ferro-magnesian host minerals.