Muscovite - Phengite

Monoclinic  Images    

   
   
  Formula KAl2(AlSi3O10)(OH)2 - KAl2-x(Mg,Fe)x(Si3+xAlxO10)(OH)2
  Optic class & sign Biaxial negative
  Optical orientation X near c, Y near a, Z = b
  Optical plane Orthogonal to (010), close to (100)
  Relief Low- to moderate-positive
  Refractive indices nx = 1.547 -1.580
ny = 1.582 -1.620
nz = 1.587 -1.624
n increases with Fe2+, Mg, Fe3+, Mn, Cr, V, Ti
  Birefringence   (max.)0.035  - 0.049
   
  Optic Angle 2Vx = 24 - 47°, 3T Mus 0°; 2V decreases with increasing impurities; phengite 0 - 20°
2Vz
  Sign of elongation Length-slow, l (+) in sections at high angles to (001)
  Interference figure Acute bisectrix figures with multiple isochromes in sections Ʇ c
  Colour /   pleochroism Colourless; fuchsite is pale green pleochroic
  Zoning 

  Form  Habit Flaky to platy
  Surface Typically subhedral with well-developed (001) crystal faces
  Cleavage {001} perfect
  Twinning Twinning on {001} may be present, but can only be observed in sections close to (010) if extinction to cleavage traces deviates from 0°.
  Extinction Straight or nearly straight to {001} traces; max angle ca. 3°.
Characteristic “bird’s-eye-maple” mottled structure.

  Reaction textures  Hydrous breakdown product of feldspars, andalusite, kyanite, sillimanite
  Alteration /   decomposition Highly weathering-resistant; sericite is itself a common alteration product.

  Occurence     Ign Aluminous granites; pegmatites
  Met Abundant in sub-greenschist to amphibolite facies metapelites; impure quartzites
  Sed As an alteration or weathering product (sericite) or a detrital component in clastic sediments
  Hyd Greisen, veins; common alteration product of feldspars
  Other 

  Distinctive   properties               Habit, single perfect cleavage, high Δn and lack of colour; mottled extinction (a property shared with other sheet silicates).
Talc, pyrophyllite and pure phlogopite may be hard to distinguish optically from muscovite. Occurrence may give clues. Paragonite and muscovite/phengite cannot be distinguished optically, but are easily distinguishable by XRD.
  Additional   comments The “bird’s eyes” are a preparation effect relating to minute indentations along the lower and upper grain surfaces exposed during grinding. A high-quality polish can reduce that effect significantly.