Chlorite

Monoclinic  Images    

   
   
  Formula (Mg,Fe2+,Al,Fe3+)6(Si,Al)4O10(OH)8
  Optic class & sign Biaxial positive or negative
  Optical orientation X near a or c, Y = b, Z near c or a
  Optical plane (010)
  Relief Low-positive to high
  Refractive indices nx = 1.562 -1.671
ny = 1.565 -1.684
nz = 1.565 -1.685
n increases with increasing Fe, Mn, Cr, Al (Tschermak substitution)
  Birefringence   (max.)0.00  - 0.02, commonly below 0.012
   Δn decreases from MgAl-rich Chl to intermediate composition with Δn = 0, then increases to Fe-rich and/or Al-poor Chl.
Characteristic anomalous interference colours of brown, violet and steel blue are associated with low-birefringent varieties that are close to optical isotropy.
  Optic Angle 2Vx = 0 - 20°
2Vz = 0 - 70°
  Sign of elongation Length-fast, l (-): opt. negative; length-slow, l (+): opt. positive varieties
  Interference figure Acute bisectrix figures in (001) sections, with broad, diffuse isogyres
  Colour /   pleochroism Typically pleochroic in shades of green (opt. pos.: X ≈ Y > Z; opt. neg.: Z ≈ Y > X). Oxidation results in brown colours. Mg-rich chlorite is colourless.
  Zoning 

  Form  Habit Platy, flaky, intergrown fine-grained aggregates. worm-like stacks
  Surface Subhedral, anhedral, euhedral
  Cleavage (001) perfect
  Twinning Multiple twins on (001); can only be observed in sections close to (010) if extinction to cleavage traces deviates from 0°.
  Extinction Inclined to straight. Max extinction angle is 9°. “Bird’s-eye-maple” mottled structure.

  Reaction textures  Hydrous breakdown product of garnet and other Fe-Mg silicates
  Alteration /   decomposition May show oxidation effects, but otherwise relatively stable

  Occurence     Ign Only as secondary alteration or weathering product
  Met Metapelites and metabasites from lowest grade to greenschist/amphibolite facies transition; serpentinites
  Sed Common constituent of argillaceous sediments and sedimentary rocks
  Hyd Amygdales and fractures in volcanic rocks, hydrothermal veins, exhalites, black smokers at MOR, propylitic alteration zones of ore deposits
  Other 

  Distinctive   properties                Habit, single perfect cleavage, colour, low Δn, anomalous interference colours, mineral association. Mottled extinction (a property shared with other sheet silicates).
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