Glaucophane - Riebeckite

Monoclinic  Images    

   
   
  Formula Na2(Mg,Fe2+)3(Al,Fe3+)2Si8O22(OH)2
  Optic class & sign Biaxial positive or negative
  Optical orientation Highly variable:
X near a, Y = b, Z near c (“G” orientation)
X near a, Y near c, Z = b (“C” orientation)
X near c, Y near a, Z = b (“O” orientation)
X near c, Y = b, Z near a (“R” orientation)
  Optical plane (010) for G or R orientation, or Ʇ (010) for C and O orientation
  Relief Moderate to high
  Refractive indices nx = 1.594 -1.702
ny = 1.612 -1.712
nz = 1.618 -1.722
n increases with increasing Fe2+ for Mg and Fe3+ for Al
  Birefringence   (max.)0.006  - 0.025
   Δn decreases with increasing Fe2+ along the Glc – Rie join; Δn decreases with increasing Fe3+ along the Glc – MgRie join. Masking of interference colour by mineral colour may occur in strongly coloured varieties.
  Optic Angle 2Vx = 90 - 0°
2Vz = 0 - 90°
  Sign of elongation Length-slow, l (+), and/or length-fast, l (-), depending on composition
  Interference figure 2V highly variable; very strong dispersion for intermediate compositions very much limits the use of optic axis figures in polychromatic light.
  Colour /   pleochroism Colourless (close-to-endmember glaucophane) to strongly coloured and pleochroic in vivid blue and violet
Pleochroism: X = yellow, Y = pale lavender to violet, Z = pale to bright blue (Glc); Z = yellow-brown, Y = dark-gray blue, X = dark blue (Rie); absorption in relation to crystallographical directions: a < b ≈ c (valid for all indicatrix orientations)
  Zoning 

  Form  Habit Columnar, long-prismatic, acicular, asbestiform (crocidolite); 4-sided diamond-shaped or 6-sided cross-sections Ʇ c
  Surface Typically subhedral to euhedral
  Cleavage 2 sets {110} perfect, at 122 and 58° (seen in sections Ʇ c). In prismatic sections, the traces of the two principal cleavage sets are parallel.
  Twinning Simple or multiple on {100}, uncommon
  Extinction Inclined; generally small, c Λ with closest indicatrix axis (X, Y, or Z) = 6 - 10°

  Reaction textures  Prograde: replacement of low-pressure mafic minerals; retrograde: replacement of omphacite in eclogite, replacement of Na-amphibole by actinolite
  Alteration /   decomposition Relatively stable

  Occurence     Ign Alkaline intrusives (Rie); rare in volcanics
  Met Glc: blueschists, high-pressure marble; Rie: iron stones, granite gneiss, quartzite, granulite
  Sed 
  Hyd 
  Other 

  Distinctive   properties               Distinctive colour and pleochroism, habit, including characteristic basal sections, either diamond-shaped or six-sided combination of {110} and {010} faces; characteristic amphibole cleavage
  Additional   comments Although petrographically useful, the term ‘crossite’ for intermediate compositions in the glaucophane – riebeckite composition plane has been officially abandoned.