Lepidolite - Zinnwaldite

Monoclinic  Images    

   
   
  Formula K(Li,Al)3(Si,Al)4O10(F,OH)2 - K(Li,Fe2+,Al)3(Si,Al)4O10(F,OH)2
  Optic class & sign Biaxial negative
  Optical orientation X near c, Y = b, Z near a
  Optical plane (010)
  Relief Low-negative to low-positive
  Refractive indices nx = 1.528 -1.557
ny = 1.548 -1.585
nz = 1.551 -1.588
n increases with increasing Fe and Mn; n decreases with increasing substitution of F for OH
Lpd: nx = 1.528 - 1.540, ny = 1.548 - 1.559, nz = 1.551 - 1.567
Znw: nx = 1.542 - 1.557, ny = 1.567 - 1.585, nz = 1.570 - 1.588
  Birefringence   (max.)0.022  - 0.032
   Lpd: 0.022 - 0.032; Znw: 0.029 - 0.032
  Optic Angle 2Vx = 2M: 27 - 50°, 3T varieties: 0°
2Vz
  Sign of elongation Length-slow, l(+)
  Interference figure (001) sections yield centred acute bisectrix figures (or uniaxial figures if 2V = 0) with first- to second-order isochromes
  Colour /   pleochroism Lpd: Colourless; strongly coloured varieties may show pleochroism to pale violet or pale green. Znw: colourless to pale grey-brown. Absorption Z ≥ Y > X.
  Zoning 

  Form  Habit Hexagonal-platy, fine-grained scaly aggregates
  Surface Typically subhedral
  Cleavage {001}
  Twinning {001} rare
  Extinction Lpd: max 0 – 7°, up to 10° in Znw

  Reaction textures  Replacement by muscovite
  Alteration /   decomposition Relatively stable

  Occurence     Ign Granitic pegmatites, also in granites
  Met 
  Sed 
  Hyd Veins
  Other 

  Distinctive   properties               Low relief; colour (if visible), other properties are very similar to muscovite; restricted occurrence.
  Additional   comments Stoichiometry: The octahedral positions are commonly not completely filled.
The pink colour of lepidolite is due to Mn2+.
In the n-Δn chart, reference data for polylithionite (Pln), KLi2Al(Si4O10)F2, trilithionite (Trl), KLi1.5Al1.5(AlSi3O10)F2, and muscovite (Ms) are shown. A second n-Δn chart shows data for the more exotic Li micas ephesite, NaLiAl2(Al2Si2O10)(OH)2, Masutomilite KLiAlMn(AlSi3O10)F2, and tainiolite, KLiMg2(Si4O10)F2, with the lepiidolite (Lpd) and zinnwaldite (Znw) fields for reference.