Witherite

Orthorhombic  Images    

   
   
  Formula BaCO3
  Optic class & sign Biaxial negative
  Optical orientation X = c, Y = b, Z = a
  Optical plane (010)
  Relief Low-negative to high
  Refractive indices nx = 1.529
ny = 1.676
nz = 1.677
n decreases with increasing Sr for Ba
  Birefringence   (max.)0.148
   
  Optic Angle 2Vx = 16° - 
2Vz
  Sign of elongation Length-fast, l (-), parallel to cleavage traces, but hardly applicable due to very high Δn
  Interference figure Sections ⊥ c yield acute bisectrix figures with numerous isochromes
  Colour /   pleochroism Colourless
  Zoning -

  Form  Habit Stubby pseudohexagonal dipyramidal shapes, granular, columnar, fibrous
  Surface Euhedral to anhedral
  Cleavage {010}
  Twinning {110} always present; cyclic twins with six segments
  Extinction Straight to {010} cleavage traces and prism faces; symmetrical to pyramid faces

  Reaction textures  
  Alteration /   decomposition Baryte; witherite can be itself an alteration product of baryte

  Occurence     Ign 
  Met 
  Sed Carbonaceous Ba-rich shale and chert
  Hyd Low-temperature hydrothermal veins and cavities in calcareous sedimentary rocks
  Other 

  Distinctive   properties               Extreme Δn with high-order white interference colours and marked change of relief with rotation in sections sub-parallel to c, single cleavage, cyclic twinning. Optical properties similar to aragonite. Distinction from other carbonates also possible using staining techniques.
  Additional   comments n-Δn chart: Arg - aragonite, Cer - cerussite, Str - strontianite, Wth - witherite